Reactions Of Alkenes And Alkynes Pdf

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Just as alkenes, alkynes can be hydrated by two different methods. The direct addition of water catalyzed by mercury II salts yields the Markovnikov product.

In chemistry , an alkene is a hydrocarbon that contains a carbon —carbon double bond.

Electrophilic Addition Reactions of Alkynes

The principal reaction of the alkynes is addition across the triple bond to form alkanes. These addition reactions are analogous to those of the alkenes. Alkynes undergo catalytic hydrogenation with the same catalysts used in alkene hydrogenation: platinum, palladium, nickel, and rhodium. Hydrogenation proceeds in a stepwise fashion, forming an alkene first, which undergoes further hydrogenation to an alkane. This reaction proceeds so smoothly that it is difficult, if not impossible, to stop the reaction at the alkene stage, although by using palladium or nickel for the catalyst, the reaction can be used to isolate some alkenes. Greater yields of alkenes are possible with the use of poisoned catalysts.

Summary Sheet: Reactions of Alkenes

Addition of strong acids to alkynes is quite similar to the addition of strong acids to alkenes. Addition to alkenes is usually not stereospecific, whereas alkynes usually undergo anti addition. Strong acids usually protonate alkenes on their less substituted carbon thus developing a positive charge on the more substituted carbon of the reacting double bond. This intermediate carbocation may rearrange or simply pick up a nucleophile to form the expected addition product. The situation with alkynes is different.


We discuss this alkene reaction in Chapter What Is a Reaction Mechanism? A reaction mechanism describes in detail how a chemical reaction occurs. It.


Summary Sheet: Reactions of Alkenes

Reactions of Alkynes. A carbon-carbon triple bond may be located at any unbranched site within a carbon chain or at the end of a chain, in which case it is called terminal. Since the most common chemical transformation of a carbon-carbon double bond is an addition reaction, we might expect the same to be true for carbon-carbon triple bonds.

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Unit: Alkenes and alkynes

Ionic Organic Mechanisms pp Cite as. Unable to display preview. Download preview PDF. Skip to main content. This service is more advanced with JavaScript available. Advertisement Hide. Electrophilic Addition Reactions of Alkenes and Alkynes.

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Alkenes have double bonds; alkynes have triple bonds. Both undergo addition reactions. 2. 4-methylpentyne. 3. No; a triply bonded carbon atom can.


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